鋰鹽陰離子和不同側基的15-冠-5系冠醚對鋰鹽/冠醚固態配合物遠紅外位移的影響

溫永紅； 楊恩波； 傅立安； 方勝強；

蘭州大學化學化工學院； 中國原子能科學研究院； 蘭州大學化學化工學院 蘭州730000； 北京102413； 蘭州730000；

摘要 Two reduced sequences of(s/s′)f (relative reduced partition function ratio) found in the present paper are LiSCN·B15C5>LiCCl3COO·B15C5 > LiClO4·B15C5 and LiClO4·4-mB15C5>LiClO4·B15C5>LiClO4·Ph15C5,respectively.These solid lithium complexes with crown ethers were separated from tetrahydrofuran for the first sequence and from 3-methyl-1-butanol for the second one,respectively.Acording to the analysis of the data obtained,an independent character of the three factors(solvents,anion of lithium salts,and the sidegroup of 15C5 series),playing a part in contribution to(s/s′)f,have been brought to light preliminarily.

關鍵詞 鋰鹽/冠醚的固態配合物； 遠紅外位移； 鋰同位素； 相對約化配分函數比(s/s′)f；

論文　稀土冠醚配合物的研究XX_Schiff堿型_省略_苯并15-冠-5稀土配合物.caj